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Book 3: Fire, Volume 4 is a DVD containing episodes sixteen to twenty-one from Book Three: Fire and bonus material.
- "The Southern Raiders"
- "The Ember Island Players"
- "Sozin's Comet, Part 1: The Phoenix King"
- "Sozin's Comet, Part 2: The Old Masters"
- "Sozin's Comet, Part 3: Into the Inferno"
- "Sozin's Comet, Part 4: Avatar Aang"
- Special features: Creators, voice director, cast, and crew commentary.
- Extras: Avatar Mini Comic Book: "Private Fire, Volume 4".